• 文献标题:   Practical Chemical Sensors from Chemically Derived Graphene
  • 文献类型:   Article
  • 作  者:   FOWLER JD, ALLEN MJ, TUNG VC, YANG Y, KANER RB, WEILLER BH
  • 作者关键词:   hydrazine, micro hot plate, nitrogen dioxide, ammonia, 2 4dinitrotoluene
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Calif Los Angeles
  • 被引频次:   948
  • DOI:   10.1021/nn800593m
  • 出版年:   2009

▎ 摘  要

We report the development of useful chemical sensors from chemically convened graphene dispersions using spin coating to create single-layer films on interdigitated electrode arrays. Dispersions of graphene in anhydrous hydrazine are formed from graphite oxide. Preliminary results are presented on the detection of NO2, NH3, and 2,4-dinitrotoluene using this simple and scalable fabrication method for practical devices. Current versus voltage curves are linear and ohmic in all cases, studied independent of metal electrode or presence of analytes. The sensor response is consistent with a charge transfer mechanism between the analyte and graphene with a limited role of the electrical contacts. A micro hot plate sensor substrate is also used to monitor the temperature dependence of the response to nitrogen dioxide. The results are discussed in light of