• 文献标题:   Interaction of iron phthalocyanine with the graphene/Ni(111) system
  • 文献类型:   Article
  • 作  者:   MASSIMI L, LISI S, PACILE D, MARIANI C, BETTI MG
  • 作者关键词:   angularresolved photoelectron spectroscopy arpes, buffer layer, graphene, moleculesubstrate interaction
  • 出版物名称:   BEILSTEIN JOURNAL OF NANOTECHNOLOGY
  • ISSN:   2190-4286
  • 通讯作者地址:   Univ Roma La Sapienza
  • 被引频次:   15
  • DOI:   10.3762/bjnano.5.34
  • 出版年:   2014

▎ 摘  要

Graphene grown on crystalline metal surfaces is a good candidate to act as a buffer layer between the metal and organic molecules that are deposited on top, because it offers the possibility to control the interaction between the substrate and the molecules. High-resolution angular-resolved ultraviolet photo electron spectroscopy (ARPES) is used to determine the interaction states of iron phthalocyanine molecules that are adsorbed onto graphene on Ni(111). The iron phthalocyanine deposition induces a quenching of the Ni d surface minority band and the appearance of an interface state on graphene/Ni(111). The results have been compared to the deposition of iron phthalocyanine on graphene/Ir(111), for which a higher decoupling of the organic molecule from the underlying metal is exerted by the graphene buffer layer.