▎ 摘　　要

A consolidated effect of anharmonicity, crystallite size and defects has been studied using temperature dependent Raman spectroscopy of reduced graphene oxide (rGO). The micro-Raman spectra obtained over a wide temperature range of 173-723 K (below and above room temperature) indicate linear shifts in the peak position of G- and D- modes, with negative temperature coefficients of -0.009 and -0.010 cm(-1) K-1, respectively. The average crystallite size and defect density were calculated and their correlation with the temperature coefficient of G-peak position and line width were discussed. Further, contributions from true-anharmonic and quasi-harmonic parts in shifting the G- and D- peak positions were estimated using theoretical models, which indicate the dominance of true-anharmonic part. Role of electron-phonon, anharmonicity and defect contributions to the temperature dependent variation of line width of G-peak have been discussed. (C) 2021 Elsevier Ltd. All rights reserved.