• 文献标题:   Preparation of uniform flower-like CuO and flower-like CuO/graphene composite and their application in lithium ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN H, FENG F, HU ZL, LIU FS, GONG WQ, XIANG KX
  • 作者关键词:   lithium ion batterie, anode material, cuo microsphere, graphene
  • 出版物名称:   TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
  • ISSN:   1003-6326 EI 2210-3384
  • 通讯作者地址:   Hunan Univ Technol
  • 被引频次:   15
  • DOI:   10.1016/S1003-6326(11)61495-7
  • 出版年:   2012

▎ 摘  要

Flower-like CuO and flower-like CuO/graphene composite were prepared successfully by hydrothermal method. They were characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorption, temperature-programmed reduction, and thermogravimetric analysis. It is found that the flower-like CuO microspheres, which are composed of CuO nanosheets, possess an average diameter of 4.2 mu m and a Brunauer-Emmett-Teller surface area of 12.6 m(2)/g. Compared with the flower-like CuO, the obtained flower-like CuO/graphene composite shows an enhanced electrochemical performance with a higher capacity of 603 mA.h/g at 0.1 C rate and 382 mA.h/g at 1 C rate, and exhibits a better cycle stability with a high capacity retention of 95.5 % after 50 cycles even though at 1 C rate.