• 文献标题:   Li2S nano spheres anchored to single-layered graphene as a high-performance cathode material for lithium/sulfur cells
  • 文献类型:   Article
  • 作  者:   SUN D, HWA Y, SHEN Y, HUANG YH, CAIRNS EJ
  • 作者关键词:   lithium batterie, energy storage, sulfur, lithium sulfide, graphene, carbon coating
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Univ Calif Berkeley
  • 被引频次:   41
  • DOI:   10.1016/j.nanoen.2016.05.033
  • 出版年:   2016

▎ 摘  要

Fully lithiated lithium sulfide (Li2S) has become a promising cathode material for Li/S cells due to its high theoretic capacity (1166 mA h g(-1)) and specific energy (2600 W h kg(-1)). However, low utilization of sulfur and poor rate capability still hinder the practical application of Li/S cells. In this paper, a carbon coated Li2S/graphene composite (Li2S/G@C) was developed by incorporating Li2S nano spheres with single-layered graphene and further forming a durable protective carbon layer on the surface of the Li2S particles using a facile CVD method. The high rate capability and remarkable cycle life of the Li2S/G@C cathode were demonstrated, which was mainly attributed to the unique structure of the Li2S/G@C that can significantly improve not only the electrical conductivity, but also the mechanical stability of the sulfur cathode. (C) 2016 Elsevier Ltd. All rights reserved.