• 文献标题:   Facile synthesis of layered Zn2SnO4/graphene nanohybrid by a one-pot route and its application as high-performance anode for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   SONG WT, XIE J, HU WY, LIU SY, CAO GS, ZHU TJ, ZHAO XB
  • 作者关键词:   graphene, zinc stannate, nanohybrid, electrochemical performance, in situ route
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   48
  • DOI:   10.1016/j.jpowsour.2012.11.090
  • 出版年:   2013

▎ 摘  要

A Zn2SnO4-nanocrystals/graphene-nanosheets (Zn2SnO4/G) nanohybrid has been prepared by a facile in situ hydrothermal route using SnCl4 center dot 5H(2)O, ZnCl2 and graphite oxide (GO) as the precursors and N2H4 center dot H2O as the mineralizer and reducing agent. The formation of Zn2SnO4 and the reduction GO occur simultaneously during the hydrothermal process. The Zn2SnO4 nanocrystals are uniformly dispersed and immobilized by the graphene nanosheets reduced from GO. The direct restacking of the hydrophobic graphene sheets is inhibited by loading Zn2SnO4 nanocrystals as the spacers. Zn2SnO4/G shows an improved electrochemical performance than bare Zn2SnO4 due to the conducting, dispersing and immobilizing effects of graphene. (C) 2012 Elsevier B.V. All rights reserved.