▎ 摘　　要

Lithium-sulfur batteries hold great promise for serving as next generation high energy density batteries. However, the Shuttle of pdlysulfide induces rapid capacity degradation.aticl poor cycling stability of lithium sulfur tells. Herein, we proposed a unique lithium sulfur battery configuration with an ultrathin graphene oxide (GO) membrane for high stability. The oxygen electronegative atoms modifieci60 into a polar plane, and the carboxyl groups acted as ion-hopping sites of positively charged species (Lit) and rejected the transportation of negatively charged species (S-n(2-)) due to the electrostatic interactions. Such electrostatic repulsion and physical inhibition largely decreased the transferenceof polysulfides across the GO:membrane in the lithium sulfur system. Consequently, the GO membrane with highly tunable functionalizatidn properties, high mechanical strength, low electric conductivity', and facile fabrication procedure is an effective permselective separator system in lithium sulfur batteries. By the incorporation of a=permselective do membrane, the cyclic capacity decay rate is also reduced from 0.49 to 0.23%/cycle. As the GO membrane blocks the diffusion of polystilfides through the membrane, it is also with advantages of antkelfdischarge properties.