• 文献标题:   Graphene oxide nanoslit-confined AgBF4/ionic liquid for efficiently separating olefin from paraffin
  • 文献类型:   Article
  • 作  者:   YING W, PENG XS
  • 作者关键词:   graphene oxide nanoslit, ionic liquid, silver ion, olefin separation, longterm stability
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   1
  • DOI:   10.1088/1361-6528/ab53af
  • 出版年:   2020

▎ 摘  要

Facilitated transport membrane for separating light olefins, using transition metals like silver and copper as carriers, is a promising way to replace traditional energy-consuming methods. Here, we construct ionic liquid (IL) to fill the nanoslits of laminated graphene oxide (GO) membrane with silver ions as a carrier to separate ethylene/ethane. The nanoslits of GO membrane efficiently prevent the loss of silver ion IL solution. The IL further slows down the reduction of silver ions. The membrane with silver concentration of 0.25 M shows the best performance with a selectivity of 54 for ethylene/ethane and ethylene permeance of 2.9 GPU. This performance is superior to other silver ion IL solution membranes and competitive among the reported facilitated transport membranes.