• 文献标题:   Preparation of Functionalized Graphene Sheets via Microwave-Assisted Solid-State Process and Their Electrochemical Capacitive Behaviors
  • 文献类型:   Article
  • 作  者:   XUE LP, ZHENG MB, SHEN CF, LU HL, LI NW, PAN LJ, CAO JM
  • 作者关键词:   functionalized graphene sheet, microwave irradiation, supercapacitor, electrochemical measurement
  • 出版物名称:   CHINESE JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1001-4861
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   9
  • DOI:  
  • 出版年:   2010

▎ 摘  要

Functionalized graphene sheets were produced by microwave-induced exfoliation of graphene oxide. Exfoliation happens when the oxygen-containing groups decomposed into CO2 and H2O by microwave-heat, thus yielding pressures that exceed the Van der Waals attraction between the layers. X-ray diffraction, FTIR, SEM, TEM and nitrogen adsorption-desorption were used to characterize the samples. Scanning electron microscopy images show that the sample possesses nanoporous structures. Fourier-transform infrared spectroscopy characterization proves the existence of a few functional groups on the surface of graphene sheets. The results of nitrogen adsorption-desorption analysis indicate that the sample has high BET surface area (412.9 m(2).g(-1)) and large pore volume (1.91 cm(3).g(-1)). The electrochemical tests show that the sample has good electrochemical capacitive behavior and high specific capacitance values about 207.5 F.g(-1) in aqueous KOH.