• 文献标题:   Functionalization of graphene nanoplatelets using sugar azide for graphene/epoxy nanocomposites
  • 文献类型:   Article
  • 作  者:   BOSE S, DRZAL LT
  • 作者关键词:   graphene nanoparticle, sugar azide, nanocomposite, spectroscopy, thermomechanical property
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:   Michigan State Univ
  • 被引频次:   5
  • DOI:   10.5714/CL.2015.16.2.101
  • 出版年:   2015

▎ 摘  要

We report a covalent functionalization of graphene nanoparticles (GnPs) employing 2,3,4-Tri-O-acetyl-beta-D-xylopyranosyl azide followed by fabrication of an epoxy/functionalized graphene nanocomposite and an evaluation of its thermo-mechanical performance. Successful functionalization of GnP was confirmed via thermal and spectroscopic study. Raman spectroscopy indicated that the functionalization was on the edge of the graphene sheets; the basal plane was not perturbed as a result of the functionalization. The epoxy/functionalized GnP composite system exhibited an increase in flexural modulus (similar to 18%) and glass transition temperature (similar to 10 degrees C) compared to an un-functionalized GnP based epoxy composite.