• 文献标题:   Adsorption of organic solvent vapours on carbon nanotubes, few-layer graphene nanoflakes and their nitrogen-doped counterparts
  • 文献类型:   Article
  • 作  者:   KUPREENKO SY, STROKOVA NE, IL GOVA EA, IVANOV AS, ARKHIPOVA EA, SAVILOV SV
  • 作者关键词:   volatile organic compound, vapour sorption, isosteric heat of adsorption, carbon nanotube, fewlayer graphene nanoflake, nitrogen doping
  • 出版物名称:   ADSORPTIONJOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
  • ISSN:   0929-5607 EI 1572-8757
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s10450-021-00349-1 EA DEC 2021
  • 出版年:   2022

▎ 摘  要

This work studies the influence of nitrogen doping of carbon nanotubes (CNTs) and few-layer graphene nanoflakes (GNFs) on the adsorption of organic solvent vapours. The synthesized materials (CNTs, GNFs and N-doped counterparts) were thoroughly characterized by simultaneous thermal analysis, low temperature nitrogen physisorption and X-Ray photoelectron spectroscopy. The basic regularities of the adsorption of organic solvent vapours were studied using acetone, ethyl acetate, acetic acid and toluene. The dependence of the maximum adsorption capacity of CNTs, GNFs and N-doped counterparts on the dipole moment of adsorbate was investigated. The dependencies of the isosteric heat of adsorption on the degree of surface coverage for various pairs of adsorbate-adsorbent were obtained and the average values of the heat of adsorption were calculated. It was found that introduction of nitrogen into the structure of CNTs and GNFs significantly increases the heat of acetic acid vapour adsorption. [GRAPHICS]