• 文献标题:   Electrocatalytic oxidation of formaldehyde on direct electrodeposited graphene-platinum nanoparticles composites electrode
  • 文献类型:   Article
  • 作  者:   CHEN YA, LIU XH, ZHANG W, ZHANG Y, LI LJ, CAO ZZ, WANG H, JIA G, GAO YF, LIU JR
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL METHODS
  • ISSN:   1759-9660 EI 1759-9679
  • 通讯作者地址:   Inner Mongolia Univ Technol
  • 被引频次:   16
  • DOI:   10.1039/c3ay40364e
  • 出版年:   2013

▎ 摘  要

The one-step electrochemical deposition of highly dispersed platinum nanoparticles on graphene to fabricate a new Pt/EG/GC modified electrode for formaldehyde determination in aqueous solution. Catalyst surface morphology was characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM), the composition analysis was carried out on energy-dispersive X-ray spectroscopy (EDS). The electrochemical performances of the electrode were investigated by cyclic voltammetry, and clear amperometric responses were obtained in the scan process. The correlation coefficient was 0.998 of the linear relation between current values and concentrations, the Pt/EG/GC electrode exhibited a low limit of detection (0.04 mM), high sensitivity (0.0162 mA mM(-1)) and long working life. These characteristics make the Pt/EG/GC electrode appropriate for the formaldehyde determination based on formaldehyde electric catalytic oxidation.