• 文献标题:   A facile hydrazine-assisted hydrothermal method for the deposition of monodisperse SnO2 nanoparticles onto graphene for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   PARK SK, YU SH, PINNA N, WOO S, JANG B, CHUNG YH, CHO YH, SUNG YE, PIAO Y
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   100
  • DOI:   10.1039/c1jm14199f
  • 出版年:   2012

▎ 摘  要

In this manuscript, we introduce a facile hydrothermal method for the controlled growth of SnO2 nanoparticles onto graphene oxide. Hydrazine plays a fundamental role in controlling the formation and crystallization of SnO2 nanoparticles, and the reduction of graphene oxide to graphene. The SnO2-graphene composite consists of 3-4 nm monodisperse SnO2 nanocrystals homogeneously dispersed at the surface of graphene. It is demonstrated that the composite can accommodate the large volume change of SnO2 which occurs during lithiation-delithiation cycles. When used as an anode material for lithium ion batteries, it exhibits a first discharge capacity of 1662 mA h g(-1), which rapidly stabilizes and still remains at 626 mA h g(-1) even after 50 cycles, when cycled at a current density of 100 mA g(-1). Even at the very high current density of 3200 mA g(-1), the composite displays a stable capacity of 383 mA h g(-1) after 50 cycles.