• 文献标题:   One-step synthesis of iodine doped polyaniline-reduced graphene oxide composite hydrogel with high capacitive properties
  • 文献类型:   Article
  • 作  者:   WANG J, LI BY, NI T, DAI TY, LU Y
  • 作者关键词:   polymer, nano composite, electrical propertie
  • 出版物名称:   COMPOSITES SCIENCE TECHNOLOGY
  • ISSN:   0266-3538 EI 1879-1050
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   20
  • DOI:   10.1016/j.compscitech.2015.01.008
  • 出版年:   2015

▎ 摘  要

Iodine doped polyaniline-reduced graphene oxide composite hydrogel was one-step synthesized using iodine as catalyst and dopant. The structure, composition and the surface morphology of the material were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectrum (FTIR), scanning electronmicroscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that the reduced graphene oxide was iodine-doped and covered uniformly by the polyaniline nanoparticles doped also with iodine. The electrochemical properties of the hydrogel were evaluated by cyclic voltammetry, galvanostatic charge/discharge and the impedance spectroscope using a symmetrical two-electrode configuration. With the enhanced specific capacitance as 712.5 F g(-1) at a current density of 1 A g(-1) and a good cycling stability about 77% (from 440 to 340 F g(-1)) after 1000 charge/discharge cycles at a current density of 8 A g(-1), the composite hydrogel exhibits great potential in the application of high-performance energy storage devices. (C) 2015 Elsevier Ltd. All rights reserved.