• 文献标题:   Water desalination using nanoporous single-layer graphene
  • 文献类型:   Article
  • 作  者:   SURWADE SP, SMIRNOV SN, VLASSIOUK IV, UNOCIC RR, VEITH GM, DAI S, MAHURIN SM
  • 作者关键词:  
  • 出版物名称:   NATURE NANOTECHNOLOGY
  • ISSN:   1748-3387 EI 1748-3395
  • 通讯作者地址:   Oak Ridge Natl Lab
  • 被引频次:   577
  • DOI:   10.1038/NNANO.2015.37
  • 出版年:   2015

▎ 摘  要

By creating nanoscale pores in a layer of graphene, it could be used as an effective separation membrane due to its chemical and mechanical stability, its flexibility and, most importantly, its one-atom thickness. Theoretical studies have indicated that the performance of such membranes should be superior to state-of-the-art polymer-based filtration membranes, and experimental studies have recently begun to explore their potential. Here, we show that single-layer porous graphene can be used as a desalination membrane. Nanometre-sized pores are created in a graphene monolayer using an oxygen plasma etching process, which allows the size of the pores to be tuned. The resulting membranes exhibit a salt rejection rate of nearly 100% and rapid water transport. In particular, water fluxes of up to 10(6) g m(-2) s(-1) at 40 degrees C were measured using pressure difference as a driving force, while water fluxes measured using osmotic pressure as a driving force did not exceed 70 g m(-2) s(-1) atm(-1).