• 文献标题:   Nanoflake delta-MnO2 deposited on carbon nanotubes-graphene-Ni foam scaffolds as self-standing three-dimensional porous anodes for high-rate-performance lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHAI X, MAO Z, ZHAO GY, ROONEY D, ZHANG NQ, SUN KN
  • 作者关键词:   lithium ion battery, threedimensional porous anode, deltamno2, highrateperformance
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   3
  • DOI:   10.1016/j.jpowsour.2018.09.057
  • 出版年:   2018

▎ 摘  要

The electrification of transportation necessitates the growth of high-power-density lithium ion batteries. However, traditional graphite anodes in lithium ion batteries perform poorly especially when charged or discharged under high current density. In this work, we deposit nanoflake delta-MnO2 on the carbon nanotubes-Graphene-Nickel foam compound matrix and apply it as a self-standing anode without binder or conductive agent. This composite buffers volume change, enables more electrochemical active sites, boosts the conductivity of electrode materials and facilitates lithium-ion diffusion. The resulting lithium ion batteries with the composite anodes show improved cycle life and enhanced rate performance, yielding a high specific capacity of 1250 mAh g(-1) for 350 cycles at 0.4 A g(-1) and 490 mAh g(-1) over 700 cycles at 4.0 A g(-1).