• 文献标题:   One-pot electrodeposition synthesis of ZnO/graphene composite and its use as binder-free electrode for supercapacitor
  • 文献类型:   Article
  • 作  者:   ZHANG Z, REN L, HAN WJ, MENG LJ, WEI XL, QI X, ZHONG JX
  • 作者关键词:   zno, energy storage, graphene, supercapacitor
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Xiangtan Univ
  • 被引频次:   33
  • DOI:   10.1016/j.ceramint.2014.11.127
  • 出版年:   2015

▎ 摘  要

A simple one-pot green electrodeposition route is presented for the synthesis of ZnO/graphene nanosheets composite. During a electrochemical deposition process, the graphene oxide nanosheets loose oxygen-containing functional group to become graphene nanosheets (GNS), and zinc oxide (ZnO) is also electrochemically deposited on the electrode. Such hybrid microstructure facilitates the charge and ion transport in the electrode, which has been observed by scanning electron microscopy. Besides, the as-prepared ZnO/GNS sample also has been characterized with X-ray powder diffraction and Raman spectra. Moreover, the electrochemical performance of the obtained composite used as supercapacitor electrode is investigated by cyclic voltanunerty, galvanostatic charge/discharge, and electrochemical impedance spectra tests. At the current density of 3 Ag-1, the resulting ZnO/GNS composite exhibits an enhanced specific capacitance of 291 Fg(-1), much larger than that of pure ZnO (118.8 Fg(-1)). (C) 2014 Elsevier Ltd and Teclma Group S.r.l. All rights reserved.