• 文献标题:   Nanospherical-Like Manganese Monoxide/Reduced Graphene Oxide Composite Synthesized by Electron Beam Radiation as Anode Material for High-Performance Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   JIANG XY, ZHU XM, LIU XL, XIAO LF, AI XP, YANG HX, CAO YL
  • 作者关键词:   manganese monoxide, graphene, lithiumion battery, electron beam radiation
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   22
  • DOI:   10.1016/j.electacta.2016.02.164
  • 出版年:   2016

▎ 摘  要

Nanospherical-like manganese monoxide/reduced graphene oxide (MnO/rGO) nanocomposites are synthesized by using an electron beam radiation approach in an aqueous solution containing potassium permanganate and graphene oxide in the presence of acetone as radical scavenger and subsequently calcining in flowing Ar atmosphere. SEM and TEM observations show that nanospherical-like MnO with average size of 20 nm are firmly anchored onto the rGO to form MnO/rGO nanocomposites. The typical MnO/rGO nanocomposite exhibits a high initial reversible capacity (977.1 mAh g(-1)) at a current density of 150 mA g(-1) and delivers 648.4 mAh g(-1) at a rate of 750 mAh g(-1) with excellent cycling performance (89% of capacity retention over 50 cycles), which indicates that the MnO/rGO nanocomposite is a promising anode candidate for Li-ion batteries. Furthermore, the facile synthetic strategy by using an electron beam radiation provides a novel avenue for making high-performance metal oxide/graphene nanocomposites for energy storage applications. (C) 2016 Elsevier Ltd. All rights reserved.