▎ 摘　　要

The influence of a graphene/silver (G/A) nanocomposite coating layer on the microstructural evolution and surface oxidation of a Mg-Ni-La hydride is investigated systematically by XRD, SEM, EDS and HRTEM in detail. SEM and EDS reveal that the existence of the G/A composite prevents the electrode from pulverizing and oxidizing. The oxygen content in the surface of the electrode is reduced from 21% to 10% after 50 cycles for a Mg-Ni-La electrode with 0.2 mass fraction of G/A. The crystallization process of the amorphous electrodes coated by G/A is reduced compared to the uncoated electrode and the stable Mg2NiH4, alpha-Mg, MgH2 and La oxihydroxide phases are present with the grain size about 40-60 nm after 50 charge/discharge cycles. The G/A coating reduces the corrosion and oxidation of the electrode alloy and provides both a pathway for hydrogen diffusion and active sites for the redox reaction of hydrogen. All of these factors result in a significant improvement of the discharge capacity by about 200 mAh g(-1) in each cycle (after activation) for Mg-Ni-La electrodes with 0.2 mass fraction of G/A nanocomposites. (C) 2016 Elsevier B.V. All rights reserved.