• 文献标题:   Graphene Quantum Dots from Partially Unzipped Multi-Walled Carbon Nanotubes: Promising Materials for Oxygen Electrodes
  • 文献类型:   Article
  • 作  者:   DANILOV MO, FOMANYUK SS, DOVBESHKO GI, GNATYUK OP, RUSETSKYI IA, KOLBASOV GY
  • 作者关键词:   graphene, luminescence, quantum dot, power source, electrocatalysi, fuel cell
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1149/1945-7111/abf4b3
  • 出版年:   2021

▎ 摘  要

Photoluminescent graphene quantum dots (GQDs) the one- or two-layer graphene nanoparticles 1.5-3 nm in size with a blue emission have been obtained from electrochemically synthesized partially unzipped multi-walled carbon nanotubes ultrasonically treated for one hour. Various physicochemical methods including photoluminescence spectroscopy, XRD, TEM, and Raman spectroscopy, have been used to characterize the electrochemically synthesized partially unzipped multi-walled carbon nanotubes and GQDs. Two-layer oxygen electrodes were fabricated, where GQDs served as an active layer. The investigations of electrocatalytic characteristics of the oxygen electrodes fabricated of the obtained materials were carried out in a fuel half-cell with an alkaline electrolyte. The fabricated oxygen electrodes were stable for six months at a discharge current density of 200 mA cm(-2). The obtained GQDs are promising materials as a new type of catalyst carriers for oxygen electrodes of fuel cells.