• 文献标题:   TiO2 Nanosheet-Redox Graphene Oxide/Sulphur Cathode for High-Performance Lithium-Sulphur Batteries
  • 文献类型:   Article
  • 作  者:   HONG S, HAN YZ, ZHANG K, WANG MB, CUI NN, DU XQ, LI QY, HUANG YG, JIANG F, XIE KY
  • 作者关键词:   lithiumsulphur batterie, composite cathode, tio2 nanosheet, polysulphide
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   0
  • DOI:   10.1166/jnn.2020.16957
  • 出版年:   2020

▎ 摘  要

Lithium-sulphur batteries are considered as some of the most potent secondary-battery systems. These batteries are expected to have extensive applications in fields requiring high-energy density. However, such applications are hindered by some serious intrinsic obstacles. Herein, TiO2 nanosheets-rGO/sulphur (TiO2 NS-rGO/S) composites were fabricated through a two-process hydrothermal method. TiO2 nanosheets served as active sites for polysulphide absorption, whereas rGO offered space for sulphur improvement and TiO2 NS-rGO/S composites. The TiO2 NS-rGO/S composite exhibited high discharge capacity of 1099 mAh.g(-1) at 0.2 C rate and retained a capacity of 690 mAh.g(-1) after 100 cycles, with high sulphur loading of 3 mg.cm(-2). The high initial specific discharge capacity and improved cyclic stability were attributed to the synergistic effects of TiO2 nanosheets and rGO. These results indicated that the simple, low-cost and scalable method provides a novel perspective on practical utilisation of lithium-sulphur batteries.