• 文献标题:   Multifunctional Property Improvements by Combining Graphene and Conventional Fillers in Chlorosulfonated Polyethylene Rubber Composites
  • 文献类型:   Article
  • 作  者:   STROMMER B, BATTIG A, FRASCA D, SCHULZE D, HUTH C, BOHNING M, SCHARTEL B
  • 作者关键词:   nanocomposite, rubber, multilayer graphene, flame retardancy, synergy, nanoparticle, elastomer
  • 出版物名称:   ACS APPLIED POLYMER MATERIALS
  • ISSN:   2637-6105
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1021/acsapm.1c01469 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

The incorporation of nanoparticles like multilayer graphene (MLG) into elastomeric composites boosts their technical performance, such as their mechanical behavior and electrical conductivity. Common filler types (carbon black (CB) and aluminum trihydroxide (ATH)) generally fulfill single, specific purposes and are often used in high loadings. CB typically reinforces rubber mechanically, while ATH increases flame retardancy. Small amounts of MLG reduce these high filler contents and maintain the multifunctional characteristics of rubber composites. In chloro-sulfonated polyethylene (CSM) + ATH, an intrinsically flame-retardant rubber was designed to achieve the highest standards such as maximum average of heat emission (MARHE) <90 kW m(-2), 3 phr MLG was substituted for 15 phr CB and/or 3 phr ATH via an industrially applicable processing approach. Replacing either CB or ATH resulted in a property profile that was multifunctionally improved in terms of features such as mechanical performance, reduced sorption, and flame retardance. MLG nanocomposites are reported to show promise as an industrially utilizable route to obtain multifunctional high-performance rubbers.