• 文献标题:   Graphene oxide-based novel MOF nanohybrid for synergic removal of Pb (II) ions from aqueous solutions: Simulation and adsorption studies
  • 文献类型:   Article
  • 作  者:   SINGH S, BASAVARAJU U, NAIK TSSK, BEHERA SK, KHAN NA, SINGH J, SINGH L, RAMAMURTHY PC
  • 作者关键词:   uio66ndc/go, pb ii, removal, isotherm, del studie, nanocomposite
  • 出版物名称:   ENVIRONMENTAL RESEARCH
  • ISSN:   0013-9351 EI 1096-0953
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.envres.2022.114750 EA NOV 2022
  • 出版年:   2023

▎ 摘  要

Heavy metals represent a considerable threat, and the current study deals with synthesizing a novel MOF nanocomposite by intercalating graphene oxide (GO) and linker UiO-66-NDC. It was shown that UiO-66-NDC/GO had enhanced the removal efficiency of Pb (II) ions at pH 6. The adsorption kinetics data followed the PSO (Type 2) representing chemisorption. Adsorption data were also fitted with three different isotherms, namely Temkin, Freundlich, & Langmuir, and the Temkin model exhibited the best correlation (R-2 0.99), representing the chemisorption nature of the adsorption process. The maximum adsorption capacity (qmax) of Pb (II) ions using Langmuir was found to be 254.45 mg/g (298 K). The Pb (II) adsorption process was confirmed to be exothermic and spontaneous as the thermodynamic parameters H degrees and G degrees were determined to have negative values. MOF nanocomposite also represents significant reusability for up to four regeneration cycles using 0.01 M HCl; for the next four, it works quite efficiently after regeneration. Meanwhile, the simulation findings confirm the superior dynamic stability (similar to 08 times) of the MOF nanocomposite as compared to the GO system. The removal of Pb (II) from simulated wastewater samples using a super nano-adsorbent using a MOF nanocomposite is described here for the first time.