• 文献标题:   Assessment of Thermoelectric, Mechanical, and Microstructural Reinforcement Properties of Graphene-Mixed Heterostructures
  • 文献类型:   Article
  • 作  者:   ZAFERANI SH, GHOMASHCHI R, VASHAEE D
  • 作者关键词:   graphene nanoplate, heterostructure composition, thermoelectric, nanostructuring, covsn
  • 出版物名称:   ACS APPLIED ENERGY MATERIALS
  • ISSN:   2574-0962
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1021/acsaem.1c00015 EA APR 2021
  • 出版年:   2021

▎ 摘  要

We examine the role of graphene nanoplates (GNPs) in the critical properties of thermoelectric GNP nanocomposites. After a detailed analysis of the thermoelectric, microstructural, and mechanical characteristics of such nanocomposites, we present a case study based on CoVSn-GNP heterostructures. It is shown that GNPs can improve the mechanical properties without deteriorating the thermoelectric properties of the material. CoVSn-GNP bulk composites are fabricated using powder metallurgy and spark plasma sintering with a GNP weight percentage range of 0-1. All samples with the addition of GNPs showed improved mechanical properties compared with pristine CoVSn. The sample with 0.5 wt % GNPs showed the highest value of Vickers Hardness (737 HV) among all of the studied compositions. Moreover, the fracture toughness was higher for the samples with a lower average crystal size. The concentration and dispersion of GNPs did not significantly change the CoVSn multiphase microstructure; however, it influenced the thermoelectric factors by reducing the thermal conductivity and increasing the Seebeck coefficient, leading to the enhancement of the thermoelectric figure of merit.