• 文献标题:   Imaging state of charge and its correlation to interaction variation in an LiMn0.75Fe0.25PO4 nanorods-graphene hybrid
  • 文献类型:   Article
  • 作  者:   ZHOU JG, WANG J, HU YF, REGIER T, WANG HL, YANG Y, CUI Y, DAI HJ
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Canadian Light Source Inc
  • 被引频次:   23
  • DOI:   10.1039/c3cc39015b
  • 出版年:   2013

▎ 摘  要

Visualization of the state of charge (SOC) in an LiMn0.75Fe0.25PO4 nanorods-graphene hybrid nanostructure (LMFP-C) is realized by chemical mapping of the Fe valance state using scanning transmission X-ray microscopy (STXM). The LMFP-graphene interaction strength variation studied by C K-edge STXM has been correlated to SOC variation, i.e. a stronger interaction was observed for sample regions with a higher SOC in LMFP. Such structure-performance correlation opens new perspectives for a rational design of a better performance olivine cathode for lithium ion batteries.