• 文献标题:   A novel electrochemical detemination platform of uranyl ion based on silver nanodendrites-reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   GUO WH, XU HL, CAO XH, MA JG, LIU YH
  • 作者关键词:   graphene oxide, silver nanodendrite, modified electrode, uranium
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:   East China Univ Technol
  • 被引频次:   0
  • DOI:   10.1016/j.microc.2020.105134
  • 出版年:   2020

▎ 摘  要

A sustainable strategy for the determination of Uranium has been suggested. More concretely, Ag nanodendrites/reduced graphene oxide (AgNDs/ERGO) nanocomposite film was prepared and used as an additive for UO22+ reduction, resulting in enhanced significant electrocatalytic performances. The nanocomposite film was prepared via an electrodeposition method and characterized by scanning electron microscopy (SEM), energy-dispersive spectrometer (EDS) and X-ray diffraction (XRD). Electrochemical impedance spectroscopy results show the AgNDs/ERGO modified electrode has lower charge transfer resistance and the cyclic voltammetry results confirm the AgNDs/ERGO modified electrode exhibits excellent electrocatalytic activity compared to the AgNDs and ERGO modified electrode. The fabricated electrode exhibits linear responses of UO22+ the over ranges of 1 x 10(-6) -2 x 10(-4) mol L-1, and the sensitivity and detection limit are calculated as 0.338 mu A cm(-2) mu M-1 and 85 mu M.