▎ 摘　　要

Mid-infrared spectroscopy is essential for chemical identification and compositional analysis because of the existence of characteristic molecular absorption fingerprints. However, it is very challenging to determine the refractive index of an analyte at low concentrations using current photonic systems in a broad mid-infrared spectral range. We propose an imaging-based nanophotonic technique for refractive index determination. The technique is based on deep subwavelength graphene plasmon nanocavities and allows for the retrieval of molecular concentration. This method features a two-dimensional array of suspended graphene plasmon nanocavities, in which the extremely high field enhancement and extraordinary compression of graphene plasmons can be realized simultaneously by combining shallow and deep cavities. This enables resonant unit cells to be read out in the spatial absorption pattern of the array at multiple spectral points, and the resulting information is then translated into the refractive index of the analytes. The proposed technique gives complementary information compared with the current nanophotonic techniques based on molecular absorption, including the ability of the refractive index measurement, the ultra-broadband measurable spectral range, and the small volume of the analyte required, thereby pushing the potential for refractometric sensing technologies into the infrared frequencies.