• 文献标题:   Structural, dielectric, and magnetic properties of reduced graphene oxide-wrapped MnFe2O4 composites synthesized by in-situ sol-gel autocombustion method
  • 文献类型:   Article
  • 作  者:   KIRAN, KUMAR S, THAKUR N
  • 作者关键词:   composite, electrical propertie, impedance, magnetic propertie
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.ceramint.2021.10.138
  • 出版年:   2022

▎ 摘  要

Herein, the reduced graphene oxide (rGO) wrapped MnFe2O4 (MFO@rGO) composites with different rGO content of 10, 20, 30, and 40 wt% have been synthesized by a one-step in-situ sol-gel autocombustion method. The synthesized composites have been tested for their structural, electrical, dielectric, and magnetic characteristics. The composites are characterized by using standard techniques (XRD, HR-TEM, FTIR, and Raman spectroscopy). The composite having 20 wt% of rGO exhibits the highest value of dielectric constant (epsilon'similar to 1.32 x 10(4) at 100 Hz, epsilon'similar to 143 at 1 MHz) and dc conductivity (sigma(dc) = 4.31 x 10(-6) Omega(-1)-cm(-1)) among the investigated composites. The dipole polarization contribution to the dielectric relaxation behavior of MFO@rGO composites is observed, which arises from the increased vacancy defect dipoles in rGO sheets. The impedance studies show the existence of two different time relaxation phenomena in MFO@rGO composites. The magnetic measurements reveal the superparamagnetic behavior of composites. The saturation magnetization of composites decreases first with the increase in rGO content up to 20 wt% and then increases with a further increase in rGO content. The findings of this research make these composites a potential candidate for various applications such as EMI shielding and energy storage devices.