• 文献标题:   Nanofabrication of Heteromolecular Organic Nanostructures on Epitaxial Graphene via Room Temperature Feedback-Controlled Lithography
  • 文献类型:   Article
  • 作  者:   WANG QH, HERSAM MC
  • 作者关键词:   graphene, scanning tunneling microscopy, nanolithography, selfassembled monolayer, organic functionalization
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Northwestern Univ
  • 被引频次:   44
  • DOI:   10.1021/nl103590J
  • 出版年:   2011

▎ 摘  要

Nanoscale control of surface chemistry holds promise for tailoring the electronic, optical, and chemical properties of graphene. Toward this end, the nanofabrication of sub-5-nm heteromolecular organic nanostructures is demonstrated on epitaxial graphene using room temperature ultrahigh, vacuum scanning tunneling microscopy, In particular,monolayers of the organic semiconductor 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) are nanopattemed on.epitardal graphene:using feedback-controlled lithography (FCL) and then used as chemical resists to template the deposition of N,N'-diocty1-3,4,9,10-perylene-tetracarboxylic diimide (PTCDI-C8). The generality of this FCL-based nanofabrication procedure suggests its applicability to a wide range of fundamental studies and prototype device fabrication on chemically functionalized graphene.