• 文献标题:   Facile synthesis of laminated graphene for advanced supercapacitor electrode material via simultaneous reduction and N-doping
  • 文献类型:   Article
  • 作  者:   TIAN GY, LIU L, MENG QH, CAO B
  • 作者关键词:   ndoped graphene, melamineresorcinolformaldehyde, specific capacitance, electrode material
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   32
  • DOI:   10.1016/j.jpowsour.2014.10.171
  • 出版年:   2015

▎ 摘  要

The restacking-inhibited N-doped graphene (GN) is prepared for supercapacitor material based on the sol gel method. Meanwhile, the graphene oxide (GO) is reduced and modified by melamine-resorcinolformaldehyde (MRF). The reduced graphene oxide (RG) is characterized with the ultraviolet visible absorption spectrum, Raman spectra and X-ray diffraction. Moreover, the morphology of GN is measured by scanning electron microscopy, transmission electron microscopy and nitrogen adsorption. The doped N content is confirmed by elemental analysis and X-ray photoelectron spectroscopy. The result shows that GO is reduced by resorcinol derivatives. With the specific surface of 518 m(2) g(-1) and N content of 9.77 wt%, laminated GN with 2.5 wt% GO exhibits the outstanding specific capacitance (245 F g(-1)), low chargetransfer resistance and superior cycle stability (94.8% retention after 2000 cycles). (C) 2014 Elsevier B.V. All rights reserved.