• 文献标题:   Highly-efficient forward osmosis membrane tailored by magnetically responsive graphene oxide/Fe3O4 nanohybrid
  • 文献类型:   Article
  • 作  者:   RASTGAR M, SHAKERI A, BOZORG A, SALEHI H, SAADATTALAB V
  • 作者关键词:   forward osmosi, thin film nanocomposite, graphene oxide, magnetic field, water flux, permeability
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   6
  • DOI:   10.1016/j.apsusc.2018.02.118
  • 出版年:   2018

▎ 摘  要

Emerging forward osmosis (FO) process as a potentially more energy efficient method has recently gained remarkable attention. Herein, considering the unique features of graphene oxide (GO), a new facile method has been proposed to magnetically modify GO within the polyamide active layer to obtain highly efficient osmotically driven membranes. While exposed to magnetic field, thin film nanocomposite membranes modified by GO/Fe3O4 nanohybrids (TFN-MMGO/Fe3O4) were synthesized by in-situ interfacial polymerization of the prepared monomer solution and organic trimesoyl chloride. Water permeability, salt rejection, and fouling tendency of the modified membranes were then evaluated and compared with both pristine thin film composite (TFC) membrane and the ones modified by GO/Fe3O4 nanohybrides in the absence of magnetic field (TFN-GO/Fe3O4). According to the experimental results, when compared to the TFC and TFN-GO/Fe3O4 membranes, respectively, 117.4% and 63.2% water flux enhancements were achieved in TFN-MMGO/Fe3O4 membrane with optimal GO/Fe3O4 nanohybrid concentration of 100 ppm. In spite of such improvements in water flux, little compromise in reverse salt leakages were observed in the TFN-MMGO/Fe3O4 membranes compared to the TFC one. As well, the TFN-MMGO/Fe3O4 and TFN-GO/Fe3O4 membranes revealed higher fouling resistances than the TFC membrane due to their distinguished manipulated surface characteristics. (C) 2018 Elsevier B.V. All rights reserved.