• 文献标题:   A simple and sensitive resonance Rayleigh scattering-energy transfer method for amino acids coupling its Ruhemann's purple and graphene oxide probe
  • 文献类型:   Article
  • 作  者:   LUO YH, LI CN, QIN AM, LIANG AH, JIANG ZL
  • 作者关键词:   graphene oxide, amino acid, ninhydrin, resonance rayleigh scatteringenergy transfer
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:   Guangxi Normal Univ
  • 被引频次:   3
  • DOI:   10.1016/j.jlumin.2017.01.016
  • 出版年:   2017

▎ 摘  要

In pH 7.2 KH2PO4-NaOH buffer solution, graphene oxide (GO) has strong resonance Rayleigh scattering (RRS) effect at 400 nm, and amino acid reacted with ninhydrin to form blue-violet complex Ruhemann's purple (RP) with a absorption peak at 400 nm. RPs can strongly adsorbed on the surface of GO, and the RRS donor of GO probes coupled with the receptor of RP that reduced the RRS intensity at 400 nm due to the RRS-energy transfer (RRS-ET) from the GO to RR With the increase of amino acid concentration, the RRS intensity quenched linearly at 400 nm due to the RRS-ET enhancing. The quenched intensity responds linearly with glutamic acid concentration in the range of 0.2-200 mu mol L-1, with a detection limit of 0.08 mu mol L-1. This simple and sensitive RRS-ET method was used to detect the content of amino acid in oral liquid, with satisfactory results. (C) 2017 Elsevier B.V. All rights reserved.