• 文献标题:   Functionalized ionic liquid-assisted mechanochemical synthesis of graphene nanosheet/polypyrrole nanocomposites
  • 文献类型:   Article
  • 作  者:   LU XJ, HE W, DOU H, YANG SD, HAO L, ZHANG F, SHEN LF, ZHANG XG
  • 作者关键词:   polypyrrole, graphene nanosheet, polymeric composite, nanocomposite
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   7
  • DOI:   10.1016/j.matlet.2011.12.037
  • 出版年:   2012

▎ 摘  要

This study describes a simple and effective ionic liquid (IL)-assisted mechanochemical route to prepare a set of nanostructured graphene nanosheet/polypyrrole (GNS/PPy) composites of with different PPy loading. The functionalized IL 1-butyl-3-methylimidazolium tetrachloroferrate (Bmim[FeCl4]) used here acts as not only the dispersant of GNS but also the catalyst and dopant in the synthesis of PPy. FTIR illustrates the presence of PPy in the composites. A comparative study performed on composites and pure PPy has led to two main conclusions: on one hand, the microstructure of the GNS/PPy composites is dependent on the loading of PPy. On the other hand. GNS/PPy composites show improved conductivity and thermal stability compared with pure PPy. (C) 2011 Elsevier B.V. All rights reserved.