• 文献标题:   Nitrogen-doped graphene nanosheets as cathode materials with excellent electrocatalytic activity for high capacity lithium-oxygen batteries
  • 文献类型:   Article
  • 作  者:   LI YL, WANG JJ, LI XF, GENG DS, BANIS MN, LI RY, SUN XL
  • 作者关键词:   lithium batterie, energy conversion, graphene, nitrogendoped graphene, oxygen reduction
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Univ Western Ontario
  • 被引频次:   198
  • DOI:   10.1016/j.elecom.2012.01.023
  • 出版年:   2012

▎ 摘  要

Nonaqueous lithium-oxygen battery with nitrogen-doped graphene nanosheets (N-GNSs) as cathode materials delivered a discharge capacity of 11660 mAh g(-1), which is about 40% higher than that with the pristine graphene nanosheets (GNSs). The electrocatalytic activity of N-GNSs for oxygen reduction in the nonaqueous electrolyte is 2.5 times as that of GNSs. The excellent electrochemical performance of N-GNSs is attributed to the defects and functional groups as active sites introduced by nitrogen doping. (C) 2012 Elsevier B.V. All rights reserved.