• 文献标题:   Modification of Graphene/SiO2 Interface by UV-Irradiation: Effect on Electrical Characteristics
  • 文献类型:   Article
  • 作  者:   IMAMURA G, SAIKI K
  • 作者关键词:   graphene, defect formation, field effect transistor, carrier doping, photochemical reaction, raman spectroscopy
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Univ Tokyo
  • 被引频次:   18
  • DOI:   10.1021/am5071464
  • 出版年:   2015

▎ 摘  要

Graphene is a promising material for next-generation electronic devices. The effect of UV-irradiation on the graphene devices, however, has not been fully explored yet. Here we investigate the UV-induced change of the field effect transistor (FET) characteristics of graphene/SiO2. UV-irradiation in a vacuum gives rise to the decrease in carrier mobility and a hysteresis in the transfer characteristics. Annealing at 160 degrees C in a vacuum eliminates the hysteresis, recovers the mobility partially, and moves the charge neutrality point to the negative direction. Corresponding Raman spectra indicated that UV-irradiation induced D band relating with defects and the annealing at 160 degrees C in a vacuum removed the D band. We propose a phenomenological model for the UV-irradiated graphene, in which photochemical reaction produces dangling bonds and the weak sp(3)-like bonds at the graphene/SiO2 interface, and the annealing restores the intrinsic graphene/SiO2 interface by removal of such bonds. Our results shed light to the nature of defect formation by UV-light, which is important for the practical performance of graphene based electronics.