• 文献标题:   Synthesis of graphene/DPA composite for determination of nicotine in tobacco products
  • 文献类型:   Article
  • 作  者:   JING YQ, YU BH, LI PH, XIONG B, CHENG YY, LI YG, LI CG, XIAO XY, CHEN MQ, CHEN LY, ZHANG Y, ZHAO MQ, CHENG CC
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Henan Agr Univ
  • 被引频次:   1
  • DOI:   10.1038/s41598-017-13716-2
  • 出版年:   2017

▎ 摘  要

In this contribution, the azo dye (E)-1-(4-((4-(phenylamino) phenyl) diazenyl) phenyl) ethanone (DPA) was combined with reduced graphene oxide (RGO) for the electrochemical modification of a pencil graphite electrode (RGO/DPA/PGE) surface. A series of electrochemical measurements were used for the characterization of the modified electrode surfaces. At the modified electrode, nicotine was irreversibly reduced. An obvious increase was observed in the reductive peak current of nicotine at the modified electrode, indicating the capability of the RGO/DPA composite to increase the electron transfer rate. The current was found proportional to the nicotine concentration in a range of 31 to 1900 mu M, and the limit of detection (LOD) was calculated as 7.6 mu M.