• 文献标题:   Composite organogels of graphene and activated carbon for electrochemical capacitors
  • 文献类型:   Article
  • 作  者:   ZHOU QQ, GAO J, LI C, CHEN J, SHI GQ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   47
  • DOI:   10.1039/c3ta11438d
  • 出版年:   2013

▎ 摘  要

We report the preparation of composite organogels of reduced graphene oxide (rGO) and activated carbon (AC) by a solvothermal reaction and their application as electrodes of electrochemical capacitors (ECs). In these organogels, rGO sheets are assembled into a 3-dimensional (3D) framework for encapsulating AC particles. The 3D interconnected rGO network increased the electrical conductivity and the AC component provided high specific surface areas (SSAs) for the composite organogels. These composite organogels also have stable mechanical properties and can be directly used as electrodes of ECs without using any binding agent and conducting additive. In a practical two-electrode system, the specific capacitance of the ECs based on the composite organogels was tested to be 116.5 +/- 2.2 F g(-1) at a current density of 1 A g(-1) in an organic electrolyte of propylene carbonate (PC) containing 1 M tetraethylammonium tetrafluorobromate (TEABF(4)). These ECs also exhibited a high energy density of 12.5 Wh kg(-1) even at a high power density of 6216 W kg(-1). They also showed a much larger volumetric specific capacitance compared with that of the EC based on rGO organogel and a much higher specific capacitance and rate capability than those of the AC-based EC.