• 文献标题:   Free-standing carbon nanotube/graphene hybrid papers as next generation adsorbents
  • 文献类型:   Article
  • 作  者:   DICHIARA AB, SHERWOOD TJ, BENTONSMITH J, WILSON JC, WEINSTEIN SJ, ROGERS RE
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Rochester Inst Technol
  • 被引频次:   31
  • DOI:   10.1039/c4nr01028k
  • 出版年:   2014

▎ 摘  要

The adsorption of a series of aromatic compounds from aqueous solution onto purified, free-standing single-walled carbon nanotube/graphene nanoplatelet hybrid papers is studied both experimentally and theoretically. Experimental data is obtained via changes in optical absorption spectra of the aqueous solutions and is used to extract all parameters required to implement a semi-empirical mass-transfer model. Agreement between experiment and theory is excellent and data from all compounds can be cast on a universal adsorption curve. Results indicate that the rate of adsorption and long-time capacity of many aromatic compounds on hybrid paper adsorbent significantly exceeds that of activated carbon by at least an order of magnitude. The combination of carbon nanotubes and graphene also promotes on the order of a 25% improvement in adsorption rates and capacities than either component alone. Hybrid nanocomposites show significant promise as adsorption materials used for environmental remediation efforts.