• 文献标题:   Engineering high charge transfer n-doping of graphene electrodes and its application to organic electronics
  • 文献类型:   Article
  • 作  者:   SANDERS S, CABREROVILATELA A, KIDAMBI PR, ALEXANDERWEBBER JA, WEIJTENS C, BRAEUNINGERWEIMER P, ARIA AI, QASIM MM, WILKINSON TD, ROBERTSON J, HOFMANN S, MEYER J
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Univ Cambridge
  • 被引频次:   23
  • DOI:   10.1039/c5nr03246f
  • 出版年:   2015

▎ 摘  要

Using thermally evaporated cesium carbonate (Cs2CO3) in an organic matrix, we present a novel strategy for efficient n-doping of monolayer graphene and a similar to 90% reduction in its sheet resistance to similar to 250 Ohm sq(-1). Photoemission spectroscopy confirms the presence of a large interface dipole of similar to 0.9 eV between graphene and the Cs2CO3/organic matrix. This leads to a strong charge transfer based doping of graphene with a Fermi level shift of similar to 1.0 eV. Using this approach we demonstrate efficient, standard industrial manufacturing process compatible graphene-based inverted organic light emitting diodes on glass and flexible substrates with efficiencies comparable to those of state-of-the-art ITO based devices.