• 文献标题:   Ultrathin Flexible Graphene Film for High-Performance Electromagnetic Interference Shielding via Infrared-Assisted Rapid Thermal Shock Exfoliation
  • 文献类型:   Article
  • 作  者:   ZOU K, GE JL, YAN KL, QI GC, ZHANG XH, GAO L, BAO NZ
  • 作者关键词:  
  • 出版物名称:   INDUSTRIAL ENGINEERING CHEMISTRY RESEARCH
  • ISSN:   0888-5885
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acs.iecr.2c00730 EA JUN 2022
  • 出版年:   2022

▎ 摘  要

Lightweight, flexible, and high-strength electromagnetic interference (EMI) shielding materials with high shielding effectiveness (SE) are desirable for portable/wearable electronics. Here, we reported an efficient synthesis of a highly aligned conductive graphene film by an infrared-assisted rapid thermal shock exfoliation. Benefiting from its noncontact thermal radiation heating with a homogeneous and efficient thermal field, gas is rapidly generated from graphene oxide films. This results in a sharp increase in the interlayer pressure and thus forms a mesoporous interlayer structure, which could be compressed into compact films with enhanced conductivity and mechanical strength. A relatively low-temperature treatment at 1500 degrees C healed partial defects in graphene sheets and gave an ultrathin (similar to 10 mu m) graphene film with remarkable properties of high electrical conductivity of similar to 1500 S cm(-1), a high EMI SE of 52 dB in the X band, and high tensile strength of up to 160 MPa. This time-saving fabrication process makes graphene film a competitive candidate for practical EMI shielding applications.