• 文献标题:   Functionalized graphene oxide cross-linked poly (2,6-dimethyl-1,4-phenylene oxide)-based anion exchange membranes with superior ionic conductivity
  • 文献类型:   Article
  • 作  者:   ZHANG DJ, XU SC, WAN RY, YANG YF, HE RH
  • 作者关键词:   graphene oxide, composite anion exchange membrane, crosslinking, ionic conductivity
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:  
  • 被引频次:   17
  • DOI:   10.1016/j.jpowsour.2021.230720 EA NOV 2021
  • 出版年:   2022

▎ 摘  要

Composite anion exchange membranes (AEMs) with superior conductivity are developed by cross-linking of ammonium quaternized poly(2,6-dimethyl-1,4-phenylene oxide) (QPPO) with tertiary amine groups function-alized GO (NGO). Compared to the pristine QPPO membrane, the fabricated composite anion exchange mem-branes (QPPO-NGO(x), x refers to the NGO mass percentage in the membrane) exhibit less water uptake and swelling ratio but higher ion conductivity and alkaline stability. A hydroxide conductivity as high as 123 mS cm(-1) is reached by the proposed composite membrane at 80 degrees C. The conductivity of about 83 mS cm(-1) is retained after the composite membrane immersed in 2 mol L-1 KOH aqueous solutions at 60 degrees C for 384 h. While the QPPO membrane turns into fragile after soaked in alkaline solutions for only 144 h. The single fuel cell based on the QPPO and QPPO-NGO(2) membranes demonstrates a peak power density of 289.3 mW cm(-2) at 0.53 V and 397.8 mW cm(-2) at 0.61 V, respectively, at 60 degrees C feeding with humidified hydrogen and oxygen under a back pressure of 0.1 MPa.