• 文献标题:   A glucose biosensor based on TiO2-Graphene composite
  • 文献类型:   Article
  • 作  者:   JANG HD, KIM SK, CHANG H, ROH KM, CHOI JW, HUANG JX
  • 作者关键词:   glucose biosensor, tio2gr composite, aerosol assisted selfassembly, cyclic voltammetry
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Korea Inst Geosci Mineral Resources
  • 被引频次:   145
  • DOI:   10.1016/j.bios.2012.05.033
  • 出版年:   2012

▎ 摘  要

A novel glucose biosensor was developed based on the adsorption of glucose oxidase at a TiO2-Graphene (GR) nanocomposite electrode. A TiO2-GR composite was synthesized from a colloidal mixture of TiO2 nanparticles and graphene oxide (GO) nanosheets by an aerosol assisted self-assembly (AASA). The particle morphology of all TiO2-GR composites was spherical in shape. It was observed that micron-sized TiO2 particles were encapsulated by GR nanosheets and that the degree of encapsulation was proportional to the ratio of GO/TiO2. The amperometric response of the glucose biosensor fabricated by the TiO2-GR composite was linear against a concentration of glucose ranging from 0 to 8 mM at -0.6 V. The highest sensitivity was noted at about 6.2 mu A/mM cm(2). The as prepared glucose biosensor based on the TiO2-GR composite showed higher catalytic performance for glucose redox than a pure TiO2 and GR biosensor. (C) 2012 Elsevier B.V. All rights reserved.