• 文献标题:   Three-dimensional sp(2)-hybridized carbons consisting of orthogonal nanoribbons of graphene and net C
  • 文献类型:   Article
  • 作  者:   HU M, DONG X, YANG BC, XU B, YU DL, HE JL
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Yanshan Univ
  • 被引频次:   7
  • DOI:   10.1039/c5cp01621e
  • 出版年:   2015

▎ 摘  要

We identify two sp(2) hybridized network models of carbon, namely GT-8 and CT-12, based on first-principles calculation results. Parallel nanoribbon rows of graphene and net C are found to be interlinked with orthogonal nanoribbons to construct GT-8 and CT-12, and their series of isomorphic analogs ( named GTs and CTs) are assembled with the widening of the nanoribbon components. GTs and CTs are dynamically and mechanically stable and energetically more favorable than many previous sp(2) carbons, including K-4, C20, and H6 carbon. They are two-dimensional conductors with insulating properties along the z-axis. Remarkably, GTs are superconductive with increased superconducting transition temperatures, T-c, as the nanoribbons widen. The T(c)s of GT-8 and GT-16 are 5.2 and 14.0 K respectively, which are higher than that of boron-doped diamond under the same value of Coulomb pseudopotential mu(star). They possess higher bulk moduli than graphite and behave as excellent ductile materials. The Young's modulus of GT-8 along the z-axis is comparable with that of graphene and it significantly increases as the nanoribbons widen.