• 文献标题:   Introduction of a new dichlorophen electrochemical sensor relying on the modified glassy carbon electrode (GCE) with carboxyl-functionalized graphene oxide/poly (L-arginine)
  • 文献类型:   Article
  • 作  者:   EBRAHIMI P, GHOLIVAND MB
  • 作者关键词:   dichlorophen, polylarginine, carboxylfunctionalized graphene oxide, electrochemical determination
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s10008-022-05323-7 EA NOV 2022
  • 出版年:   2023

▎ 摘  要

Dichlorophen (Dcp), a harmful environmental pollutant, is broadly utilized in veterinary medications, chemical fertilizers, pesticides, cosmetics, and personal care products. The current work reports a low-cost, simple, and convenient technique to achieve an electrochemical sensor relying on the electropolymerization of poly-L-arginine (PLA) on carboxyl-functionalized graphene oxide (COOH-GO)-modified GCE for the detection of Dcp. The stepwise assembly procedure and electrochemical characteristics of the fabricated sensor were studied by FTIR, FESEM, EIS, and CV. The resulting PLA/COOH-GO-modified electrode showed a well-defined irreversible peak to Dcp with a broad linear range over 0.01-1.5 and 1.5-60 mu M with a low detection limit of 3 nM. Finally, the fabricated sensor was successfully utilized for the quantitation of Dcp in spiked river water with satisfying results. This sensor also displayed desirable anti-interference performance and long-term stability.