• 文献标题:   One-Pot Decoration of Graphene with SnO2 Nanocrystals by an Elevated Hydrothermal Process and Their Application as Anode Materials for Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   KONG Z, LIU DD, LIU XH, FUG AP, WANG YQ, GUO PZ, LI HL
  • 作者关键词:   tin dioxide, graphene, elevated hydrothermal synthesi, anode material, lithium ion battery
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   7
  • DOI:   10.1166/jnn.2019.15889
  • 出版年:   2019

▎ 摘  要

Tin dioxide (SnO2), with a high theoretical storage capacity of 782 mAhg(-1), is a potential alternative anode for rechargeable lithium ion batteries (LIBs). However, its low electronic conductivity and poor stability during cycling (due to a change in volume) hinder its practical applications for energy storage. Composite materials of SnO2-nanocrystal-decorated graphene, which show excellent electrochemical characteristics, were prepared using a one-pot elevated hydrothermal method at 250 degrees C without subsequent carbonization treatment. The effects of graphene, solvent composition, and temperature on the morphology, structure, and electrochemical properties of the SnO2/graphene composites were investigated using XRD, SEM, TEM, and N-2 adsorption-desorption techniques. The as-prepared SnO2/graphene composites deliver a high initial discharge capacity of 1734.1 mAh g(-1) at 200 mA g(-1) and exhibit a high reversible capacity of 814.7 mAh g(-1) even after 70 cycles at a current density of 200 mA g(-1). The composites also exhibit a high rate capability of 596 mAh g(-1) at 2000 mAg(-1), indicating a long cycle life and promising capability when used as anode materials for lithium ion batteries and suggesting that SnO2/graphene composites have wide application prospects in LIBs.