• 文献标题:   Ethylenediamine-Functionalized Reduced Graphene Oxide for Enhanced Methylene Blue Removal
  • 文献类型:   Article
  • 作  者:   ZHANG JY, WANG CB, ZHOU JW
  • 作者关键词:   adsorption, graphene, methylene blue, modification
  • 出版物名称:   ENVIRONMENTAL ENGINEERING SCIENCE
  • ISSN:   1092-8758 EI 1557-9018
  • 通讯作者地址:   Xinxiang Univ
  • 被引频次:   6
  • DOI:   10.1089/ees.2016.0262
  • 出版年:   2017

▎ 摘  要

Ethylenediamine-functionalized reduced graphene oxide (GO) was synthesized by reacting chlorine-functionalized reduced GO and ethylenediamine. Chlorine atoms in reduced GO are susceptible to substitution by ethylenediamine, thereby causing their elimination. The product exhibits improved efficiency in methylene blue (MB) removal. Adsorption kinetics of the reaction fit a pseudo-second order model. Adsorption isotherms of MB on the product could be well described by the Langmuir model; physisorption may dominate the adsorption process. Batch experiments show an adsorption capacity of 143.6 mg/g, which is superior to those of reduced GO (77.2 mg/g) and activated carbon (AC, 46.5 mg/g).