• 文献标题:   SnO2 Nanoparticle-Decorated Graphene Oxide Sheets Efficiently Catalyze Baeyer-Villiger Oxidation with H2O2
  • 文献类型:   Article
  • 作  者:   ZHENG WG, TAN R, LUO XF, XING C, YIN DH
  • 作者关键词:   lewis acid catalysi, heterogeneous catalysi, oxidation
  • 出版物名称:   CATALYSIS LETTERS
  • ISSN:   1011-372X EI 1572-879X
  • 通讯作者地址:   Hunan Normal Univ
  • 被引频次:   9
  • DOI:   10.1007/s10562-015-1639-8
  • 出版年:   2016

▎ 摘  要

Uniform rutile SnO2 nanoparticles with small size (ca. 3 nm) were highly dispersed on both sides of GO sheets through electrostatic interactions, giving pseudo-homogeneous catalysts of SnO2/GO nanocomposites. The SnO2-decorated GO nanocomposites, especially, SnO2 (15 wt%)/GO was highly efficient and reusable in Baeyer-Villiger oxidation of ketones with H2O2. SnO2/GO nanocomposites, where uniform SnO2 nanoparticles were tightly gripped on both sides of GO sheets by surface oxygenated functional groups through electrostatic interaction, have proved to be a versatile, efficient and reusable catalyst for the BV oxidation of ketones with H2O2. [GRAPHICS]