• 文献标题:   Photocatalytic self-cleaning electrochemical sensor for honokiol based on a glassy carbon electrode modified with reduced graphene oxide and titanium dioxide
  • 文献类型:   Article
  • 作  者:   LEI Y, YANG F, LI YT, TANG LN, CHEN KL, ZHANG GJ
  • 作者关键词:   photocatalysi, rgo, cyclic voltammetry, differential pulse voltammetry, tio2, scanning electron microscopy, transmission electron microscopy, electrochemical sensor
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Hubei Univ Chinese Med
  • 被引频次:   0
  • DOI:   10.1007/s00604-017-2239-7
  • 出版年:   2017

▎ 摘  要

The authors describe the construction of a renewable electrochemical method for determination of honokiol in complex traditional Chinese herbs. A nanocomposite consisting of reduced graphene oxide and titanium dioxide was prepared and deposited on the surface of a glassy carbon electrode (GCE). This composite endows the GCE with self-cleaning capability via ultraviolet illumination. Under optimized conditions and at a typical working voltage of 0.54 V (vs. Ag/AgCl), the sensor has a linear response in the 0.025 to 10 mu mol center dot L-1 honokinol concentration range, and the detection limit is 20 nmol center dot L-1 (at an S/N ratio of 3). The method was successfully applied to the determination of honokiol in cortex herbs and its galenicals.