• 文献标题:   Solid-State Heating Synthesis of Poly (3,4-Ethylenedioxythiophene)/Gold/Graphene Composite and Its Application for Amperometric Determination of Nitrite and Iodate
  • 文献类型:   Article
  • 作  者:   ALI A, ZHANG Y, JAMAL R, ABDIRYIM T
  • 作者关键词:   solidstate method, poly 3 4ethylenedioxythiophene, composite, amperometry, ion detection
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Xinjiang Univ
  • 被引频次:   0
  • DOI:   10.1186/s11671-017-2338-8
  • 出版年:   2017

▎ 摘  要

A ternary composite of poly (3,4-ethylenedioxythiophene)/gold/graphene (PEDOT/Au/GO) for promising electrochemical sensor was synthesized by solid-state heating method. The interaction between the PEDOT, Au, and GO explored for detection of nitrite and iodate. It was found that the PEDOT/Au/GO composite had shale-like morphology with a uniform distribution of gold nanoparticles. Electrochemical experiments showed that the PEDOT/Au/GO composite modified electrode exhibited good electrocatalytic activity toward determination of iodate. The amperometric experiments at the PEDOT/Au/GO/GCE revealed that a good linear relationship existed between peak current and the concentration in the range of 100-1000 mu M with the detection of 0.53 and 0.62 mu M (S/N = 3) for nitrite and iodate, respectively. Moreover, the current response of PEDOT/Au/GO/GCE for nitrite and iodate at 10 mu M was up to 9.59 and 11.47 mu A, respectively.