▎ 摘　　要

LiFe1-xMnxPO4, which combines the advantages of excellent rate capability of LiFePO4 and high operation voltage of LiMnPO4, is widely studied as a promising cathode for the purpose of facilitating its electronic conductivity and Li-ion mobility. Herein, a double-carbon co-modified strategy is introduced to design and construct carbon-coated LiFe0.4Mn0.6PO4 enwrapped into 3D graphene framework (LiFe0.4Mn0.6PO4/C/rGO), in which a novel Fe0.4Mn0.6C2O4 center dot 2H(2)O/GO precursor is creatively introduced and synthesized via fast in-situ coprecipitation without any pH regulator. In the LiFe0.4Mn0.6PO4/C/rGO architecture, well dispersive LiFe(0.4)Mn(0.6)PO(4 )particles with submicron-size are uniformly coated by a conductive carbon layer to form LiFe0.4Mn0.6PO4/C, which are tightly anchored on and enwrapped into 3D graphene framework, guaranteeing sufficient "face-to-face" intimate contact between these three components. Benefiting from synergetic contributions from the well-designed 3D conductive network, fast Li-ion diffusion path, and unique structure for electrolyte penetration, the integrated LiFe0.4Mn0.6PO4/C/rGO yields high discharge capacity of 159.5 mAh.g(-1) at 0.05C, superior rate capacity of 118.7 mAh.g(-1) at 10C, and durable capacity retention of 96.4% after 200 cycles at 2 C. This proposed efficiency strategy can also be extended to other advanced cathodes for high-energy LIBs. (C) 2020 Elsevier Ltd. All rights reserved.